紀伊國屋書店

基本説明

Based on a classification according to metal centre of these electron-deficient compounds. The cross-referencing and index enables the reader to find the solution to the synthesis problem. Contents: Sc(III) Lewis Acids; Polymer Supported Metal Lewis Acids; and more.

Full Description

The use of Lewis acids in organic synthesis, especially in catalysis is one of the most rapidly developing fields in synthetic organic chemistry. In addition, Lewis acid catalysis is one of the key technologies for asymmetric synthesis, and combinatorial chemistry as well as for large-scale production. Until now, pertinent information on these topics was scattered throughout the literature. Although review articles have appeared,it was difficult for the researcher to compare different methods based on Lewis acids. This two-volume handbook, edited and written by an outstanding team of experts in the field, fills this gap! This book is based on a classification according to metal centre of these electron-deficient compounds, allowing an in-depth treatment of the characteristics, benefits and limitations of each class of acid. Extensive cross-referencing and a comprehensive index enables readers to quickly find the solution to their synthesis problem. The chemical community will welcome this as a source of inspiration and invaluable reference for daily work.

Contents

VOLUME 1. Li(I), Na(I), and K(I) Lewis Acids (S. Saito). Mg(II) and Zn(II) Lewis Acids (Y. Motoyama & H. Nishiyama). Achiral B(III) Lewis Acids (K. Ishihara). Chiral B(III) Lewis Acids (K. Ishihara). Achiral Al(III) Lewis Acids (T. Ooi & K. Maruoka). Chiral Aluminum Lewis Acids in Organic Synthesis (W. Wulff). Silicon(IV) Lewis Acids (M. Oishi). Sn(II) and Sn(IV) Lewis Acids (K. Ishihara). Preparation and Lewis-Acid-Promoted Addition Reactions of Allylic and Allenic Tin and Indium Reagents (J. Marshall). VOLUME 2. Sb(III) and Sb(V) Lewis Acids (K. Ishihara). Copper Lewis Acids in Organic Synthesis (M. Sibi & G. Cook). Ag(I), Au(I) Lewis Acids (A. Yanagisawa). Transition Metal Lewis Acids: From Vanadium to Platinum (E. Kundig & C. Saudan). Titanium(IV) Lewis Acids (H. Urabe & F. Sato). Chiral Ti(IV) Lewis Acids (K. Mikami & M. Terada). Hf-Centered Lewis Acids in Organic Chemistry (K. Suzuki & S. Yamanoi). Zirconium Lewis Acids (R. Hara & T. Takahashi). Sc(III) Lewis Acids (S. Kobayashi). Lanthanide Lewis Acids Catalysis (M. Shibasaki, et al.). Polymer-Supported Metal Lewis Acids (S. Itsuno). Index.